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Beilstein J. Org. Chem. 2014, 10, 442–448, doi:10.3762/bjoc.10.41
Graphical Abstract
Figure 1: A family of chiral and achiral equivalents of nucleophilic glycine.
Scheme 1: Synthesis of chiral ligands 4a–f.
Scheme 2: Preparation of diastereomeric Ni(II) complexes 5a–f and 6a–f.
Figure 2: Crystallographic structure of (SCRN)-5b.
Figure 3: Crystallographic structure of (SCRN)-5b showing an exposure of the methyl moiety of α-phenylethylam...